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111.
The objective of the 20 Nautile dives of the recent Kanaut cruise was to study the southern wall of the Kane Fracture Zone from its eastern intersection with the Mid-Atlantic Ridge (MAR) to 5 Myr in age. The geological mapping shows four successive massifs, wrench faulted and slightly tilted. The transform-facing walls of these massifs exhibit outcrops of fresh and serpentinized peridotites, gabbros and basalts. The entire crustal exposure is cataclased and metamorphosed to greenschist facies.  相似文献   
112.
A (15)N tracer study was performed during an experimental transplantation trial of natural Posidonia oceanica cuttings. The experiment was done in situ at 17 m depth in the Revellata Bay (Calvi, NW Corsica, France). Despite high survival rates of transplants (>90%) after one year, the weight and the N content of transplants are significantly lower than those of reference plants. In absence of roots, the transplants are not able to meet their N requirement, because leaf uptake is insufficient to replenish the N lost during the natural leaf decay. This could constitute a major cause of long-term failure for transplantation experiments or natural re-colonisation processes. The increase of the (15)N content in the roots shows that the plant re-allocates the nitrogen of one organ (i.e. leaves, rhizomes) to ensure the growth of another (i.e. roots).  相似文献   
113.
A rotating, acoustic gas bubble detector, BOB (Bubble OBservatory) module was deployed during two surveys, conducted in 2009 and 2011 respectively, to study the temporal variations of gas emissions from the Marmara seafloor, along the North Anatolian Fault zone. The echosounder mounted on the instrument insonifies an angular sector of 7° during a given duration (of about 1 h). Then it rotates to the next, near-by angular sector and so forth. When the full angular domain is insonified, the “pan and tilt system” rotates back to its initial position, in order to start a new cycle (of about 1 day). The acoustic data reveal that gas emission is not a steady process, with observed temporal variations ranging between a few minutes and 24 h (from one cycle to the other). Echo-integration and inversion performed on the acoustic data as described in the companion paper of Leblond et al. (Mar Geophys Res, 2014), also indicate important variations in, respectively, the target strength and the volumetric flow rates of individual sources. However, the observed temporal variations may not be related to the properties of the gas source only, but reflect possible variations in sea-bottom currents, which could deviate the bubble train towards the neighboring sector. During the 2011 survey, a 4-component ocean bottom seismometer (OBS) was co-located at the seafloor, 59 m away from the BOB module. The acoustic data from our rotating, monitoring system support, but do not provide undisputable evidence to confirm, the hypothesis formulated by Tary et al. (2012), that the short-duration, non-seismic micro-events recorded by the OBS are likely produced by gas-related processes within the near seabed sediments. Hence, the use of a multibeam echosounder, or of several split beam echosounders should be preferred to rotating systems, for future experiments.  相似文献   
114.
FeII-III hydroxycarbonate green rust GR(CO32−), FeII4 FeIII2 (OH)12 CO3·3H2O, is oxidized in aqueous solutions with varying reaction kinetics. Rapid oxidation with either H2O2 or dissolved oxygen under neutral and alkaline conditions leads to the formation of ferric oxyhydroxycarbonate GR(CO32−)∗, FeIII6 O12 H8 CO3·3H2O, via a solid-state reaction. By decreasing the flow of oxygen bubbled in the solution, goethite α-FeOOH forms by dissolution-precipitation mechanism whereas a mixture of non-stoichiometric magnetite Fe(3−x)O4 and goethite is observed for lower oxidation rates. The intermediate FeII-III oxyhydroxycarbonate of formula FeII6(1−x) FeIII6x O12 H2(7−3x) CO3·3H2O, i.e. GR(x)∗ for which x ? [1/3, 1], is the synthetic compound that is homologous to the fougerite mineral present in hydromorphic gleysol; in situ oxidation accounts for the variation of ferric molar fraction x = [FeIII]/{[FeII]+[FeIII]} observed in the field as a function of depth and season but limited to the range [1/3, 2/3]. The domain of stability for partially oxidized green rust is observed in the Eh-pH Pourbaix diagrams if thermodynamic properties of GR(x)∗ is compared with those of lepidocrocite, γ-FeOOH, and goethite, α-FeOOH. Electrochemical equilibrium between GR(x)∗ and FeII in solution corresponds to Eh-pH conditions close to those measured in the field. Therefore, the reductive dissolution of GR(x)∗ can explain the relatively large concentration of FeII measured in aqueous medium of hydromorphic soils containing fougerite.  相似文献   
115.
An investigation of trace metal distributions in the Western Mediterranean Sea was carried out during the RRS Discovery cruise (July 1993) in which a transect from the Strait of Gibraltar to the Strait of Sicily was conducted. Organically complexed dissolved trace metals and their total concentrations were measured to investigate the end-members and to predict the environmental capacity of the Mediterranean for potential toxic metals. The distribution of trace metals can be accounted for by the mixing of several end-members and by some atmospheric inputs to the surface water. For Pb and Fe, the effects of the atmospheric inputs are more pronounced than for the other metals. Due to the rapid exchange of water masses, the Western Mediterranean may have the ability to assimilate the increased external inputs for some trace metals such as Cu, Cd, Ni and Zn. But the external inputs for Pb and Fe exceed the removal capacity of the Western Mediterranean and these elements may accumulate in the water column of the western basin. The C18 Sep-Pak technique and direct determination by DPASV were used to determine the amount of trace metal–organic complexes. The C18 Sep-Pak column isolates only a small fraction of trace metals except for Cu. The maximum hydrophobic fractions for the studied trace metals, except for Cd and Pb, which are not detectable, were found in the subsurface layer at all stations. This maximum may well be linked to picoplankton activity and the picoplankton, prochlorophytes may have an important role in the speciation of dissolved Cu as well as Synechococcus. These organic ligands for Cu were produced at the maximum of biological activity in the Western Mediterranean basin and seem to be accumulated at halocline level by Mediterranean hydrodynamic characteristics. However, direct determination by DPASV showed that the major part of Cu, Cd and Pb, complexed by organic materials, was not isolated by C18 Sep-Pak technique.  相似文献   
116.
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